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Topic: Pressure Equilibrium Problem  (Read 2451 times)

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Offline jpmiller89

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Pressure Equilibrium Problem
« on: September 01, 2010, 10:05:59 PM »
I'm in Chem 112 right now, and it's been a year since I've taken Chem 111.  I know the forum rules kind of frown upon asking questions without even starting the problem first, but I honestly don't know where to start :(

It goes like this:

A vessel is filled with NOBr to 0.762 atm and 65.1% decomposes.  Determine Kp for this reaction:

2NOBr(g) ::equil::2NO(g) + Br2(g)

I tried doing the equilibrium equations and stuff like that, but I just don't know where to incorporate the percentage of decomposition within the whole picture :\

Offline jpmiller89

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Re: Pressure Equilibrium Problem
« Reply #1 on: September 01, 2010, 10:24:42 PM »
I think I might know.

Like, what I did, was this:

(.762*.651)*2/3 for 2NO

And then the same for Br2 but multiplied by 1/3 to get the atms.  Am I doing it right?


Offline Borek

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Re: Pressure Equilibrium Problem
« Reply #2 on: September 02, 2010, 02:49:30 AM »
I am not sure why you are multiplying by 2/3.

Start with simple stoichiometry - you know how much decomposed, that is enough to calculate final moles of each substance at equilibrium. Knowing moles you can calculate final pressure (hint: vessel is closed, so V=const).
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