For 6 and 7, the answers are correct, although you should realize, especially for 7, the difference between formal or initial concentration and the equilibrium concentration. For 7, the initial concentration of uric acid was 2M, but the equilibrium concentration is not. Hence x
2/ 2 = 1.29 * 10
-4 is not correct. Nevertheless, your answer and the actual answer is very close to each other, which is why I consider it correct. More importantly... [H
+][OH
-] / [HA] = Ka is wrong. You're implying in both 6 and 7 that [H
+] = [OH
-], which is clearly wrong. Review your book on weak acid dissociation. Your professor probably looked at this and counted it wrong.
8 has ammonia, which is a base. Again, [H
+] does not equal [OH
-]. Review what Ka and Kb mean for weak acids and weak bases.
17 Again, [H
+] does not equal [OH
-] which does not equal [HCOOH]. Don't confuse stoichiometry with equilibrium concentrations. If you have a reaction of the form
A
B + C
where A, B, and C are the substrates, and the coefficients are all 1, that does NOT mean that [A] =
= [C]. What it means is that for one molecule of A that undergoes this reaction, one molecule of B and one molecule of C are formed.