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Topic: Do nonionizable compounds have a pKa?  (Read 3975 times)

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Offline Meera

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Do nonionizable compounds have a pKa?
« on: January 24, 2011, 11:23:18 PM »
I know pKa has to do with dissociation of an acid into ions, so my instinct would be to say that nonionizable compounds don't have a pKa, but is it even possible for something to NOT have a pKa?

And it's impossible to make a salt of a nonionizable compound, right?


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Offline AWK

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Re: Do nonionizable compounds have a pKa?
« Reply #1 on: January 25, 2011, 02:41:56 AM »
Quote
And it's impossible to make a salt of a nonionizable compound, right?

http://en.wikipedia.org/wiki/N-Butyllithium
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Offline sjb

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Re: Do nonionizable compounds have a pKa?
« Reply #2 on: January 25, 2011, 04:53:34 AM »
http://en.wikipedia.org/wiki/N-Butyllithium

I suppose what this comes down to, is what is meant by a "non-ionisable compound". Sure, butane isn't likely to exist as an ion pair, but you can draw resonance forms etc that show it as such, and they all contribute something (not a lot, perhaps), to the structure.

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