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Topic: O-tolidine to O-toluidine  (Read 7068 times)

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Offline limpet chicken

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O-tolidine to O-toluidine
« on: August 28, 2005, 06:58:32 PM »
I am fairly annoyed right now, after finding that the chemical supplier that I had rather expensively, had an order shipped to an associate in the US, due to the firm not shipping to the UK, then reshipped, sold me O-tolidine, instead of the required O-toluidine.

Question is, isn't o-tolidine just two toluidines hooked together? I seem to remember that it is, I looked online for structures, and didn't find one I could view correctly, as my PC graphics drivers are currently buggered, so, how to cleave the tolidine, to toluidine?

Before it is mentioned, I am aware of the toxic and carcinogenic nature of toludine, but it is indispensible for the synthesis I am currently attempting.
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Offline hmx9123

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Re:O-tolidine to O-toluidine
« Reply #1 on: August 28, 2005, 10:27:39 PM »
Quote
isn't o-tolidine just two toluidines hooked together?

Correct.  The two amine groups are para to the linkage between the two rings.

Offline limpet chicken

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Re:O-tolidine to O-toluidine
« Reply #2 on: August 29, 2005, 12:26:00 AM »
Hmm, do you know of any way to accomplish the ahem,  cleavage ;D
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Offline limpet chicken

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Re:O-tolidine to O-toluidine
« Reply #3 on: September 10, 2005, 09:08:24 PM »
Anybody? I really need to find out how to cleave the tolidine, and I cannot find anything on wetdreams, the Hive archives, Rhodium, or even google, it just pulls up references to azo-dyes :(
The light blinds
So behold darkness as our new light
In our darkness we can see
So with others blindness
We take flight.

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