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Topic: Reversible Reactions  (Read 3022 times)

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Offline student33

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Reversible Reactions
« on: June 10, 2011, 07:37:59 PM »
Hi,

I need help with the integration reversible reactions.
I know that for a reversible reaction where A <-> C (forward reaction has a rate constant of k1 and the reverse reaction has a rate constant of k-1), the reaction rates are:

d[A]/dt = -k1[A] + k-1[C]

and

d[C]/dt = k1[A] - k-1[C]

If the initial condition is that [A]o = [A] + [C]

Then,

d[A]/dt = -k1[A] + k-1([A]o-[A])

I don't get how the integration of this equation will give me:

[A] = [Ao] (k-1 + k1e-(k1-k-1)t)/(k1 + k-1)

Any help will be appreciated.

Offline Jorriss

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Re: Reversible Reactions
« Reply #1 on: June 11, 2011, 02:18:22 AM »

Offline slavinzing56

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Re: Reversible Reactions
« Reply #2 on: July 04, 2011, 04:12:28 AM »
Jorriss  : Wow thanks!

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