September 22, 2024, 01:35:54 PM
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Topic: Polarimetry  (Read 3559 times)

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Offline BluePill

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Polarimetry
« on: June 25, 2011, 09:35:54 AM »
Here's the question:

Suppose you place a sample of sugar in a polarimeter and observe a rotation of 90 degrees, how can you be sure the sample isn't rotating the plane of pol light by -270 degrees( both would give the same reading on polarimeter)
propose a way (in theory or experiment) that you could discern between these possibilities

I'm thinking of hydrolyzing it then look at the rotation after hydrolysis. Is that correct?

Offline Borek

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Re: Polarimetry
« Reply #1 on: June 25, 2011, 10:18:13 AM »
What should happen if you dilute the solution?
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Offline BluePill

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Re: Polarimetry
« Reply #2 on: June 25, 2011, 10:20:17 AM »
Observed rotation would decrease right?

Offline BluePill

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Re: Polarimetry
« Reply #3 on: June 25, 2011, 10:27:16 AM »
I find the question a little vague as well. My first interpretation was my answer and another was a mixture of enantiomers. But I got your point Borek.

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