November 24, 2024, 06:59:20 AM
Forum Rules: Read This Before Posting


Topic: Polarimetry  (Read 3573 times)

0 Members and 1 Guest are viewing this topic.

Offline BluePill

  • Full Member
  • ****
  • Posts: 100
  • Mole Snacks: +6/-2
  • Gender: Male
  • Difficult is never synonymous to impossible.
Polarimetry
« on: June 25, 2011, 09:35:54 AM »
Here's the question:

Suppose you place a sample of sugar in a polarimeter and observe a rotation of 90 degrees, how can you be sure the sample isn't rotating the plane of pol light by -270 degrees( both would give the same reading on polarimeter)
propose a way (in theory or experiment) that you could discern between these possibilities

I'm thinking of hydrolyzing it then look at the rotation after hydrolysis. Is that correct?

Online Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27861
  • Mole Snacks: +1813/-412
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Polarimetry
« Reply #1 on: June 25, 2011, 10:18:13 AM »
What should happen if you dilute the solution?
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline BluePill

  • Full Member
  • ****
  • Posts: 100
  • Mole Snacks: +6/-2
  • Gender: Male
  • Difficult is never synonymous to impossible.
Re: Polarimetry
« Reply #2 on: June 25, 2011, 10:20:17 AM »
Observed rotation would decrease right?

Offline BluePill

  • Full Member
  • ****
  • Posts: 100
  • Mole Snacks: +6/-2
  • Gender: Male
  • Difficult is never synonymous to impossible.
Re: Polarimetry
« Reply #3 on: June 25, 2011, 10:27:16 AM »
I find the question a little vague as well. My first interpretation was my answer and another was a mixture of enantiomers. But I got your point Borek.

Sponsored Links