July 03, 2024, 01:35:03 AM
Forum Rules: Read This Before Posting


Topic: What does the "initial reaction rate" for calculating rate laws measure?  (Read 2500 times)

0 Members and 1 Guest are viewing this topic.

Offline miaou5

  • Regular Member
  • ***
  • Posts: 23
  • Mole Snacks: +0/-1
I know that the "initial reaction rate" for calculating rate laws can only be determined experimentally, but I'm a bit confused...what is it measuring exactly? It's given as moles/L per sec, but moles/L of...what? Products being formed? (E.g., if I had a reaction going, what exactly would I measure to find the initial reaction rate?)

Sorry for starting more than a single post in one day, but I'm in a bit of a time crunch for my med tests. Thanks again in advance!

Offline gnahzmx

  • Very New Member
  • *
  • Posts: 2
  • Mole Snacks: +1/-0
Re: What does the "initial reaction rate" for calculating rate laws measure?
« Reply #1 on: October 15, 2011, 10:20:03 AM »
It can measure either the product formation or starting material disappearance. The unit should be mol/L per time unit.

Offline juanrga

  • Full Member
  • ****
  • Posts: 231
  • Mole Snacks: +16/-11
    • juanrga - sharing unified knowledge in pure and applied sciences
Re: What does the "initial reaction rate" for calculating rate laws measure?
« Reply #2 on: October 16, 2011, 10:10:54 AM »
I know that the "initial reaction rate" for calculating rate laws can only be determined experimentally, but I'm a bit confused...what is it measuring exactly? It's given as moles/L per sec, but moles/L of...what? Products being formed? (E.g., if I had a reaction going, what exactly would I measure to find the initial reaction rate?)

Sorry for starting more than a single post in one day, but I'm in a bit of a time crunch for my med tests. Thanks again in advance!

Reaction rate measures the change in concentration of reactants and products with time. L is not a SI unit. The units usually are mol dm-3 s-1. The initial reaction rate is just the rate at the beginning of the reaction (i.e., when t=0).

The initial rate can be determined theoretically if you have the rate law. I think that you are referring to the experimental method named «Method of Initial Rates», which is used for determining the rate law of some reaction.
Sharing unified knowledge in pure and applied sciences

Sponsored Links