It could be deduced from dW=F.dS.
We know work equation: W=F.S.
If we differentiate this equation, we get dW=F.dS+S.dF, which is at odds with the correct expression dW=F.dS. This means the differential expression is more fundamental than the integral expression.
But why should dW be expressed as F.dS?
Is that to do with intensive property (F) which is non-integrable, and extensive property (S) which is integrable?