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Topic: IR Spectrum Alcohol/ Amine/ or both?!  (Read 5409 times)

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Offline chrisso80b

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IR Spectrum Alcohol/ Amine/ or both?!
« on: January 03, 2012, 09:41:49 AM »
Hi, I've been given an IR spectrum for a molecule and was wondering if someone could tell me how you know a molecule contains a primary amine group (which should have a stretching frequency at around 3000-3300) when the molecule also contains an -OH stretching frequency? Does the peak for the -OH group not 'hide' the smaller less intense peak of the amine group?

Thanks!

Offline Honclbrif

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Re: IR Spectrum Alcohol/ Amine/ or both?!
« Reply #1 on: January 03, 2012, 10:58:31 AM »
Could be troublesome, but you can also look for the C-N stretching around 1020-1220. Have you thought about derivatives to mask troublesome groups?
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