I think pores is the wrong concept for transferring heat. Heat is form of energy; it doesn't usually flow through the gaps in an object but through the solid part of the object. Solids and liquids in general are more efficient at transferring heat than gases.
What pores can do is allow warm gases or liquids to flow to cooler areas and use that mechanism for transferring heat. This is how skin works - the pores open up to allow water to flow from inside the body to outside the body, removing some of the body heat. This also forms a layer of water on the surface of the skin which then evaporates, removing heat from the solid portion of the skin and cooling the surface further. This combination of removing heat from inside the body by transfer in a liquid medium, combined with removing heat from the surface of the body by evaporation is how sweat cooling works.
There are a number of natural and synthetic fabrics that work the same way. They wick water from the surface of the skin which is hot, out to the surface of the fabric, where it evaporates and cools the fabric. These have been widely used in sports clothing, where they can keep you warm when you are not exercising, but don't allow the buildup of heat between your skin and your clothing when you are exercising.