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Topic: Bases  (Read 2521 times)

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Offline Kartiky14

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Bases
« on: March 14, 2012, 11:33:58 PM »
How do we determine the strength of bases?? (not alkalis)

Offline dazza95

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Re: Bases
« Reply #1 on: March 15, 2012, 07:53:18 PM »
Think in terms of ph,
pH stands for potential of hydrogen and is the measure of acidity running from 0 to 14 (the most basic or most alkaline). The lower the pH level, the more acidic the solution is as acids will have a high concentration of hydrogen ions. Pure water has a pH of 7.0 (neutral)

A solution can be described as acidic, neutral, or basic depending upon the pH level of that solution. On a chemical level under the Lowry Brønsted system an acid is defined as a proton (H+) donor, while a base (or alkali) is a proton (H+) acceptor. pH can be calculated using the formula; pH=-log10[H^+] where [H+] is the concentration of H+ ions per unit of volume. The reaction of an acid is given in the form; HA ⇌H^++A^- where HA is the acid and A- is the base. This can be placed into the equilibrium constant formula to determine the concentration of H+ ions in molar form for the pH formula.
Ka=([products])/([reactants])
Ka=([H^+ ][A^-])/([HA])
From this equation, if Ka is high then the acid is weak, if Ka is low then the acid is strong. Using this formula, the molarity of the H+ ions can be determines and then used in the pH formula. Because this equation is logarithmic it is expected that 0.1 molar of H+ ions will have a pH of 1 and if it was 0.0001 molar, it would have a pH of around 4. pKa is used more often in practice rather than Ka as it is a logarithmic measure just like pH. Every pH change of 1 means that there is 10,000 times more H+ ions per unit volume. pKa is the –log(10) of the equilibrium of the acid dissociation constant.
pKa=-log10Ka
If pKa is high then the acid is weak.

Offline PIQgoogleme

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Re: Bases
« Reply #2 on: March 15, 2012, 07:57:15 PM »
^^^
the pH scale doesn't run from 0 to 14. What if you had, say 2.0 M H2SO4 (aq)?

Find it's Kb If that doesn't mean anything to you, read up on the pH system and equilibrium constants, and come back to us with anything you're still unclear on.


Online Borek

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Re: Bases
« Reply #3 on: March 16, 2012, 04:51:50 AM »
Every pH change of 1 means that there is 10,000 times more H+ ions per unit volume.

Huh?
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