Okay, volume and shape are two extensive properties of matter. They cannot be used to identify what something is because those values change depending on the amount of a substance. I can take some silly-putty and shape it into a knife, and the take some iron metal and shape that into a knife. While the substances are completely different, their volume and shape would be the same. You can't use extensive properties to identify a substance. You can only use extensive properties to identify how MUCH of a substance you have.
The melting point of a substance is an INTENSIVE property. Intensive properties don't change no matter how much of a substance you have. You can have ten pounds of lead, or two grams of lead, and they would both have the same melting point. If you have a bunch of different metals and are told which metals you may possibly have, then you can use the melting point to differentiate between the metals. Now if you are given an unknown sample and told to identify it, then you need a bunch more INTENSIVE properties in order to conclusively identify it.
Remember, INTENSIVE properties are the same no matter how much of a unique substance you have. EXTENSIVE properties change depending on the amount of the unique substance you have.