December 22, 2024, 04:49:42 PM
Forum Rules: Read This Before Posting


Topic: Evaluating Kp  (Read 6344 times)

0 Members and 1 Guest are viewing this topic.

kandie_kane

  • Guest
Evaluating Kp
« on: November 23, 2005, 05:43:18 PM »
The question is:
Consider the equilibrium reaction
CaC03 (s) --> CaO (s) + CO2 (g)
Write the approprate expression for the thermodynamic constant, assuming that the gaseous compounds obey the ideal-gas equation of state.  Evaluate Kp at 298.15K.

I have tried this problem and have done the following

deltaG = RT ln Kp
-394.395 Kj/mol /(0.0083145 kj/mol k X 298.15 K ) = ln Kp
ln Kp= -159.08
kp =

I am unsure if I am supposed to leave out the solids in this equation or if they should be considered.  Also I unsure about the thermodynamic constant is and how to write an expression for it.

Offline Albert

  • Lonely Wanderer
  • Retired Staff
  • Sr. Member
  • *
  • Posts: 1050
  • Mole Snacks: +112/-22
  • Gender: Male
  • Half Decent Pharmaceutical Chemist
Re:Evaluating Kp
« Reply #1 on: November 25, 2005, 01:22:03 PM »
deltaG CO2 (g) = -394.4 kJ/mol
deltaG CaO (s) = -604.2 kJ/mol
deltaG CaCO3 (s) = -1128.8 kJ/mol

deltaG reaction = + 130.2 kJ/mol

deltaG reaction / (RT) = ln Keq
130.2 kJ/mol / (8.314E-3 kJ/K*mol * 298.15) = 52.525

Keq = 6.476 E+22

Sponsored Links