Many plastics and some metals resist HF, that's true. But nothing engineered by humans lasts forever, some parts will wear out, fail, and release the coolant. Then the HF is a serious risk for some metals, plastic, any silicate (including glass) and human tissue. This is why we tend to not use liquid ammonia as a coolant. Its gentler on the environment than fluorocarbons, and less expensive, but the tiniest leak is a serious odor problem.