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Topic: Δ[C]/Δt  (Read 3183 times)

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Offline Rutherford

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Δ[C]/Δt
« on: May 25, 2012, 07:27:33 AM »
In the reaction:
A+2B :rarrow: 2C
the starting concentration of substances A and B are 0.3mol/dm3 and 0.5mol/dm3. The speed constant of the reaction is 0.4dm6/mol2s. Calculate Δ [C]/Δt:
a)at the beginning of the reaction
b)after some time, when the concentration of substance A reduces by 0.1mol/dm3.

The problem is that I don't have the answer so I need someone to check my thoughts:
a)V=k[A][ B]2=Δ [C]/Δt*1/2
Δ [C]/Δt=0.06mol/dm3s
b)Same equation. but the concentrations of A and B are 0.2mol/dm3 and 0.3mol/dm3
Δ [C]/Δt=0.0072mol/dm3s
Correct?
« Last Edit: May 25, 2012, 12:01:29 PM by Borek »

Offline Rutherford

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Re: Δ[C]/Δt
« Reply #1 on: May 25, 2012, 08:48:41 AM »
V=k[A][ B]2= Δ [C]/Δt*1/2
this is the formula, didn't know why it isn't shown.
« Last Edit: May 25, 2012, 11:51:51 AM by Borek »

Offline Rutherford

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Re: Δ[C]/Δt
« Reply #2 on: May 25, 2012, 08:49:32 AM »
Why the formula isn't shown properly?

Offline Borek

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Re: Δ[C]/Δt
« Reply #3 on: May 25, 2012, 11:53:03 AM »
Strange, apparently [itex]\Delta[C[/itex] is not rendered correctly. I will try to check why.

Please remember you can format such equations using LaTeX, it will give much better results.

Δ[C
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Offline juanrga

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Re: Δ[C]/Δt
« Reply #4 on: May 27, 2012, 07:00:33 AM »
In the reaction:
A+2B :rarrow: 2C
the starting concentration of substances A and B are 0.3mol/dm3 and 0.5mol/dm3. The speed constant of the reaction is 0.4dm6/mol2s. Calculate Δ [C]/Δt:
a)at the beginning of the reaction
b)after some time, when the concentration of substance A reduces by 0.1mol/dm3.

The problem is that I don't have the answer so I need someone to check my thoughts:
a)V=k[A][ B]2=Δ [C]/Δt*1/2
Δ [C]/Δt=0.06mol/dm3s
b)Same equation. but the concentrations of A and B are 0.2mol/dm3 and 0.3mol/dm3
Δ [C]/Δt=0.0072mol/dm3s
Correct?

V=k[A][ B]2= 1/2 d[C]/dt

If you assume d[C]/dt  = Δ [C]/Δt you are basically assuming that the formation rate of C is a constant, which cannot be true because the concentrations of A and B vary with time.
« Last Edit: May 27, 2012, 07:11:48 AM by juanrga »
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Offline Rutherford

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Re: Δ[C]/Δt
« Reply #5 on: May 27, 2012, 07:39:23 AM »
The reaction goes into one direction all the time, so I thought I can use that formula. How to solve this problem then?

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