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Topic: Redox Electrode  (Read 3586 times)

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Offline Nitin_Naudiyal

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Redox Electrode
« on: June 15, 2012, 01:14:35 AM »
Fe 2+(aq) . Fe3+(aq) | Pt

The reduction reaction is given as

Fe2+ + e-  :rarrow: Fe3+ (aq)

and  Cu+(aq),Cu2+ | Pt

Cu2 + e-  :rarrow: Cu+ (aq)

in case of Fe the Fe2+ ion accepts the electron and becomes 
Fe3+.

But why does in case of Cu the Cu2+ ion accepts the Electron and becomes  Cu+

Offline Schrödinger

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Re: Redox Electrode
« Reply #1 on: June 15, 2012, 01:19:51 AM »
Fe2+ does NOT accept an electron and become Fe3+. It should be the other way around.
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Offline Borek

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Re: Redox Electrode
« Reply #2 on: June 15, 2012, 02:44:46 AM »
The reduction reaction is given as

Fe2+ + e-  :rarrow: Fe3+ (aq)

This is not reduction.

Quote
But why does in case of Cu the Cu2+ ion accepts the Electron and becomes  Cu+

There is something fishy either about the question, or about the way you posted it. Please elaborate.
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Offline Nitin_Naudiyal

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Re: Redox Electrode
« Reply #3 on: June 15, 2012, 04:01:28 AM »
They have Given the Redox electrode representation

Fe 2+(aq) . Fe3+(aq) | Pt

and then the reduction reaction for the Electrode

Fe2+ + e-  :rarrow: Fe3+ (aq)




Then they have given another Example

Cu+(aq),Cu2+ | Pt
and its reduction reaction

Cu2 + e-  :rarrow: Cu+ (aq)




i wanted to know how do these reactions occur and if one compares the reduction Reaction of Cu and Fe why are they diffrent ?

Offline AWK

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Re: Redox Electrode
« Reply #4 on: June 15, 2012, 04:11:02 AM »
Fe2+ + e- =  Fe3+ (aq)

Why not
Fe3+(aq) + e- =  Fe2+(aq)
AWK

Offline Nitin_Naudiyal

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Re: Redox Electrode
« Reply #5 on: June 15, 2012, 05:10:44 AM »
Quote
Fe2+ + e- =  Fe3+ (aq)

Why not
Fe3+(aq) + e- =  Fe2+(aq

Yes i wanted to ask this . why is this not possible.

Offline Borek

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Re: Redox Electrode
« Reply #6 on: June 15, 2012, 05:24:38 AM »
Because +2 + (-1) ≠ +3, an obvious consequence of the charge conservation.

I am not convinced you understand the notation, problem and your own question  :-\
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