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Topic: Completing reactions  (Read 2383 times)

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Offline Sanapo

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Completing reactions
« on: June 16, 2012, 01:02:57 PM »
I have to complete these two reactions:

1)  SiO2  +  C   :rarrow:  ...

2)  SiO2  +  H2O2   :rarrow:  ...

and estimate the temperature required to make them happen (if they could happen).


I guess:

1)  SiO2  +  2C   :rarrow:  Si  +  2CO

2)  SiO2  +   2H2O2   :rarrow:  Si  +  2O2  +  2H2O

I don't know if that's correct. Isn't it? How can I estimate the temperature?




Offline ramboacid

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Re: Completing reactions
« Reply #1 on: June 16, 2012, 08:53:07 PM »
Assuming that you could look up a table of standard molar enthalpies of formation and entropies of the reactants and products, and that the reactions are correct, you could calculate values of ΔH° and ΔS° for the reactions at standard conditions. Then you could calculate the temperature for which ΔG° is zero, meaning that the reaction will be at least at equilibrium. A negative value of ΔG° means that the reaction will proceed in the forward direction.

The formula relating ΔG° to ΔH° and ΔS° is: ΔG° = ΔH° - TΔS°, where T is temperature in Kelvin.
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Offline AWK

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Re: Completing reactions
« Reply #2 on: June 17, 2012, 01:03:54 PM »
1. http://en.wikipedia.org/wiki/Silicon
2. You can rather expect decomposition of H2O2
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