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Topic: Short dipole moment problem  (Read 2302 times)

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Offline Rutherford

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Short dipole moment problem
« on: August 15, 2012, 06:03:20 AM »
If the dipole moment of 1.3-dichlorobenzene is 5*10-30, what is the dipole of the ortho-isomer?

I am really stuck here, not sure what to do.

Offline sjb

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Re: Short dipole moment problem
« Reply #1 on: August 15, 2012, 06:14:06 AM »
If the dipole moment of 1.3-dichlorobenzene is 5*10-30, what is the dipole of the ortho-isomer?

I am really stuck here, not sure what to do.

I think you have to assume that the chlorines work independently, and that the hydrogens don't affect things as much

Draw something like a free-body diagram  ( http://en.wikipedia.org/w/index.php?title=Free_body_diagram&oldid=501916435 ) to work out what the dipole moment would be due to a single C-Cl, then re-evaluate given the change in geometry going from 1,3 to 1,2-dichlorobenzene

Offline Rutherford

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Re: Short dipole moment problem
« Reply #2 on: August 15, 2012, 07:32:29 AM »
Seems like this requires more geometry. I draw these diagrams, and I wrote the important angles, and using trigonometry (length of the dipole is the longest line) I got the right answer. Thanks.

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