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Topic: Unknown alum  (Read 2270 times)

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Offline Rutherford

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Unknown alum
« on: August 15, 2012, 06:10:30 AM »
When 10.3g of a metal A is melted with KHSO4, 33.4g of anhydrous alum of that metal is made (SO2 is obtained, too). Determine the metal A and write the balanced equation for the reaction.

If I assume that the metal is monovalent, then from x moles of A, x moles of KASO4 will be obtained.
x=10.3/M and x=33.4/(M+96+39)=33.4/(M+135), therefore
10.3/M=33.4/(M+135)
M=60.2g/mol which doesn't fit to any metal, if I assume that the metal was divalent, M=120.4g/mol, again nothing, and for trivalent there is no good answer. Where am I wrong?

Offline Borek

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Re: Unknown alum
« Reply #1 on: August 15, 2012, 06:15:44 AM »
First of all - alum means metal is trivalent.
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Offline Rutherford

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Re: Unknown alum
« Reply #2 on: August 15, 2012, 07:03:32 AM »
Thanks for reminding me. That way I got the correct answer, I am only unsure why when I used the equivalent mass I didn't get the right answer?

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