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Topic: how does spherical shape give lesser boiling point to alkanes?  (Read 2333 times)

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Offline Aravind

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how does spherical shape give lesser boiling point to alkanes?
« on: September 20, 2012, 09:31:25 AM »
I just read a paragraph and is confused about it in section "physical properties of alkanes" here it is :

"With increase in number of branched chains, the molecules attains the shape of a sphere.This results in smaller area of contact and therefore weak intermolecular forces between spherical molecules ,which are overcome at relatively lower temperatures"

 I think the spherical shape increases area of contact and hence attraction increases .tell me why i am wrong please

Offline Borek

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Re: how does spherical shape give lesser boiling point to alkanes?
« Reply #1 on: September 20, 2012, 09:51:24 AM »
Put two pencils and two ping pong balls close to each other. Compare contact surface.
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Offline Aravind

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Re: how does spherical shape give lesser boiling point to alkanes?
« Reply #2 on: September 20, 2012, 10:00:45 AM »
got it !! thanks!!!

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