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Topic: Kp and Kc for dehydratation  (Read 2525 times)

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Offline Rutherford

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Kp and Kc for dehydratation
« on: October 12, 2012, 10:46:32 AM »
On passing ethanol over a catalyst at 400 K, a dehydration reaction occurs resulting in the formation of ethylene:
C2H5OH(g) :rarrow: C2H4(g) + H2O(g)
At the above temperature and p0 = 101.325 kPa, the conversion of ethyl alcohol is 90.6 mol %. Calculate Kp and Kc of the reaction under given conditions and at the above temperature.

1.For Kp I got the result 4.58*p0=464kPa, I need someone to check if this is correct.

2.For Kc, to calculate the volume I need to assume that the process is isothermic and isobaric. It is isothermic because of "and at the above temperature", but how do I know that it is isobaric?

Offline curiouscat

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Re: Kp and Kc for dehydratation
« Reply #1 on: October 12, 2012, 11:48:24 AM »
I get 8.73*P0 for Part 1


Maybe I messed up...

Offline Rutherford

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Re: Kp and Kc for dehydratation
« Reply #2 on: October 12, 2012, 02:34:15 PM »
I did it through the molar shares i.e. partial pressures. In the answer it is without p0, only 4.56 and I can't see where the p0 gets reduced.

Offline outman

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Re: Kp and Kc for dehydratation
« Reply #3 on: October 13, 2012, 12:35:48 PM »
I did it through the molar shares i.e. partial pressures. In the answer it is without p0, only 4.56 and I can't see where the p0 gets reduced.

maybe the answer was wrong.

Offline Rutherford

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Re: Kp and Kc for dehydratation
« Reply #4 on: October 13, 2012, 12:52:26 PM »
Okay, then I believe that you got the same as I got.

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