Molar Heat of Solution is the change in enthalpy when one mole of a substance is dissolved into solution. So the question is asking you "What's the Delta H when you dissolved one mole of ammonium nitrate in water?". To answer your question you'll need to know the following:
specific heat capacity of water (You'll need to look this up).
the density of water (Again, you'll need to look this up).
the volume of water you used (100 mL).
the mass of ammonium nitrate you used (5.50 g)
the molecular mass of ammonium nitrate (You can calculate this; 2N, 4H, 3O)
the change in temperature. (Tf - Ti; 18.3-21.5)
With this information, you will be able to easily figure it out.
