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Topic: Oxidataion of KCN  (Read 8472 times)

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ReVeR

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Oxidataion of KCN
« on: December 27, 2005, 05:02:34 PM »
Hello.
I wanna know how to do oxidation number on something like KCN.
Basicly i figured that since CN is -1, and it got triple bond then N would be -3, C would be +2, and then K would have to be +1.
But how is something like that expressed in a Lewis diagram?
Thx

Offline Borek

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Re:Oxidataion of KCN
« Reply #1 on: December 27, 2005, 05:51:06 PM »
The problem is, ON are not the best way to describe real world.

K+ can be assigned ON of +1. As for CN- - as long as it is not necessary try to avoid using ON assigned to C or N, just treat CN- as whole group. If you really really have to do something about CN- oxidation or reduction better try other methods of redox equation balancing. Google for tutorial of half-reaction method.
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ReVeR

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Re:Oxidataion of KCN
« Reply #2 on: December 27, 2005, 06:19:45 PM »
i know how to balance them but i need to draw a lweis diagram of KCN and i donno how to do the connections....
any ideas?

Offline Borek

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Re:Oxidataion of KCN
« Reply #3 on: December 27, 2005, 06:31:27 PM »
If it helps - CN- is isoelectronic with N2.
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ReVeR

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Re:Oxidataion of KCN
« Reply #4 on: December 27, 2005, 07:56:38 PM »
How does that help me draw a lewis diagram?I can get the correct oxidataion number no problem, but i got no idea how a dot digram would look like.
« Last Edit: December 27, 2005, 07:58:11 PM by ReVeR »

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Re:Oxidataion of KCN
« Reply #5 on: January 05, 2006, 08:29:40 PM »
K+ [:C=N:]-
"Say you're in a [chemical] plant and there's a snake on the floor. What are you going to do? Call a consultant? Get a meeting together to talk about which color is the snake? Employees should do one thing: walk over there and you step on the friggin� snake." - Jean-Pierre Garnier, CEO of Glaxosmithkline, June 2006

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