The question is:
There is a reversible reaction of form aA + bB
cC + dD (a, b, c and d are stoichiometric coefficients). The rate of the forward reaction is k
1*[A]
nA*[ B]
nB (nA and nB are orders of the reaction). The rate of the backward reaction is k
2*[C]
nC*[D]
nD.
K
eq=([C]
c*[D]
d)/([A]
a*[ B]
b)
If the "rate of reaction" is defined as the rate of loss of A, then what is the differential rate equation?
I have worked out an expression for K
eq in terms of k
1, k
2 and the various concentrations, but I'm not sure how this helps me reach the differential rate equation for loss of A. That expression is:
k
1/k
2=K
eq*(([C]
nC-c*[D]
nD-d)/([A]
nA-a*[ B]
nB-b))
if you need it. Thanks for the help.
Edit: This website will provide valuable background if you have not seen it yet (look at the section on "Equilibrium reactions or opposed reactions":
http://en.wikipedia.org/wiki/Rate_equation).