June 24, 2024, 08:19:50 AM
Forum Rules: Read This Before Posting


Topic: importance of Potassium Carbonate in hydration of alkyne  (Read 3893 times)

0 Members and 1 Guest are viewing this topic.

Offline Elnaz

  • New Member
  • **
  • Posts: 5
  • Mole Snacks: +0/-0
importance of Potassium Carbonate in hydration of alkyne
« on: January 21, 2013, 09:32:39 PM »
Hi there,

I need to know the role of Potassium Carbonate in hydration of alkyne. I know if it is not added, the yield product is reduced. what product might well be expected if it were omitted?


thanks

Offline billnotgatez

  • Global Moderator
  • Sr. Member
  • ***
  • Posts: 4406
  • Mole Snacks: +223/-62
  • Gender: Male
Re: importance of Potassium Carbonate in hydration of alkyne
« Reply #1 on: January 22, 2013, 12:56:56 AM »
please read forum rules
no cross posting
I have deleted your other entry in
'    Organic Chemistry Forum for Graduate Students and Professionals
I hope you get an answer here
« Last Edit: January 22, 2013, 01:14:45 AM by billnotgatez »

Offline Dan

  • Retired Staff
  • Sr. Member
  • *
  • Posts: 4716
  • Mole Snacks: +469/-72
  • Gender: Male
  • Organic Chemist
    • My research
Re: importance of Potassium Carbonate in hydration of alkyne
« Reply #2 on: January 22, 2013, 03:23:05 AM »
I need to know the role of Potassium Carbonate in hydration of alkyne.

Under what conditions? There are several ways to hydrate an alkyne - your question is too ambiguous to answer.
My research: Google Scholar and Researchgate

Offline orgopete

  • Chemist
  • Sr. Member
  • *
  • Posts: 2636
  • Mole Snacks: +213/-71
    • Curved Arrow Press
Re: importance of Potassium Carbonate in hydration of alkyne
« Reply #3 on: January 22, 2013, 10:10:24 AM »
This looks like a procedure in which potassium carbonate was used to neutralize the acid used for the hydration of the alkyne. Given how incomplete this reaction is, I could imagine carbonate was used as a base to prevent the reaction from becoming too basic and catalyzing an aldol reaction.
Author of a multi-tiered example based workbook for learning organic chemistry mechanisms.

Offline Elnaz

  • New Member
  • **
  • Posts: 5
  • Mole Snacks: +0/-0
Re: importance of Potassium Carbonate in hydration of alkyne
« Reply #4 on: January 22, 2013, 11:33:40 AM »
Reaction's conditions come along with Hg2o and h2SO4+ H2O. After collecting distillate, we add 6.5 gr of potassium carbonate hydrate, and after dissolve we saturate the solution with sodium chloride. which is the other part of my question why we use these two compound to our distillate.
thanks orgopete. so with these explanation you still think potassium carbonate use for neutralize the acid?
thanks again for your responds.

Offline orgopete

  • Chemist
  • Sr. Member
  • *
  • Posts: 2636
  • Mole Snacks: +213/-71
    • Curved Arrow Press
Re: importance of Potassium Carbonate in hydration of alkyne
« Reply #5 on: January 22, 2013, 04:39:39 PM »
Reaction's conditions come along with Hg2o and h2SO4+ H2O. After collecting distillate, we add 6.5 gr of potassium carbonate hydrate, and after dissolve we saturate the solution with sodium chloride. which is the other part of my question why we use these two compound to our distillate.
thanks orgopete. so with these explanation you still think potassium carbonate use for neutralize the acid?
thanks again for your responds.

The crude product apparently co-distills water and some acid. The NaCl will absorb water and I think K2CO3 does as well. The K2CO3 will neutralize any acid carried over with the distillation. The K2CO3 is after the alkyne has reacted with acid, so it isn't part of an alkyne reaction.
Author of a multi-tiered example based workbook for learning organic chemistry mechanisms.

Offline Elnaz

  • New Member
  • **
  • Posts: 5
  • Mole Snacks: +0/-0
Re: importance of Potassium Carbonate in hydration of alkyne
« Reply #6 on: January 22, 2013, 05:00:57 PM »
thank you so much orgopete!

Sponsored Links