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Topic: Friedel-Crafts Acylation  (Read 2191 times)

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Offline Cooper

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Friedel-Crafts Acylation
« on: February 12, 2013, 06:15:34 PM »
Hello,

I was looking over the steps for the Friedel-Crafts acylation. I am confused on the last step. Why does it even occur? (See below) I know that the last step prevents ployacylation by making the ketone even more electron withdrawing, but I don't get why it would happen. In the first and second step (not shown) an acylium ion (C-C(triple bond)O+) is formed.

Thanks!

The image is from Organic Chemistry 10th E. by Solomons (p. 687)
~Cooper :)

Offline Cooper

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Re: Friedel-Crafts Acylation
« Reply #1 on: February 15, 2013, 05:10:27 PM »
EDIT: My professor explained to me why. It's because the AlCl3 is such a strong Lewis acid that you need to add water so that it won't stick to your product.
~Cooper :)

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