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Topic: volumetric analysis calculations  (Read 5908 times)

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biomed77

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volumetric analysis calculations
« on: January 25, 2006, 05:38:10 PM »
hello everybody, i have problems with some calculations here and i was wondering if someone could help me out.  any help is much appreciated....

calculate the molarity of an aqueous solution of sodium hydroxide if 25cm^3 of it was neutralised by 40cm^3 of 0.05mol dm^-3 nitric acid. what i did is:  0.05*40/1000=0.002 and then 0.002/0.025=0.08M  is it right???

calculate the molarity of a hydrochloric acid solution if 20cm^3 of it was neutralised by 25cm^3 of 0.4mol dm^-3 aqueous sodium hydroxide.....0.4*0.025=0.01   0.01/0.020=0.5M  is it right?


and now am struggling to find the volume of 0.2mol dm^-3 hydrochloric acid that would be required to neutralise 20cm^3 of 0.3mol dm^-3 aqueous potassium hydroxide...HELP PLZ!!!

Offline Borek

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Re:volumetric analysis calculations
« Reply #1 on: January 25, 2006, 06:29:43 PM »
0.08M  is it right???

OK

Quote
0.5M  is it right?

OK

Quote
and now am struggling to find the volume of 0.2mol dm^-3 hydrochloric acid that would be required to neutralise 20cm^3 of 0.3mol dm^-3 aqueous potassium hydroxide...HELP PLZ!!!

Start with the balanced reaction equation.
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biomed77

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Re:volumetric analysis calculations
« Reply #2 on: January 25, 2006, 06:46:11 PM »
KOH+HCL= KCL+H20.....the equals sign should be an arrow and the 2 a small 2,sorry but dont know to use it very well. anyway what do i do next???/i did 0.3*20/1000= 0.006moles  and then isaid 0.2=0.006  because the ratio is 1:1  so 0.2/0.006= 33.3cm^3   but i am not sure.. thanks for responding anyway...

Offline Borek

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Re:volumetric analysis calculations
« Reply #3 on: January 25, 2006, 07:00:10 PM »
0.3*20/1000= 0.006moles

So far so good.

Quote
the ratio is 1:1

This one is OK too.

So you are left with the question "What volume of 0.2M HCl contains 0.006 moles of acid?".

And it is not 33.3 mL.
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biomed77

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Re:volumetric analysis calculations
« Reply #4 on: January 25, 2006, 08:00:29 PM »
20*0.3= 6  so 6/0.2= 30mL         is it right now?


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