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Topic: Steric Strain Energy  (Read 7470 times)

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sci0x

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Steric Strain Energy
« on: February 10, 2006, 04:30:06 PM »
Question:
At 25degrees celcius, samples of ethylcyclohexane exist as 95% ethyl equatorial conformation and 5% ethyl axial conformation. Calculate the steric strain energy of one gauche interaction in the axial conformation of ethylcyclohexane.

Possible Answer
Well

Keg = exp(-deltaG / RT)

and Keg = (95% equatorial / 5% axial)

How do you work with these to get an answer?

Offline FeLiXe

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Re:Steric Strain Energy
« Reply #1 on: February 11, 2006, 12:43:00 PM »
how about

Keg = exp(-deltaG / RT)

and Keg = (95% equatorial / 5% axial) = 19

=>
exp(-deltaG / RT) = 19
-deltaG = RT ln(19)

I don't get the problem
Math and alcohol don't mix, so... please, don't drink and derive!

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