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Topic: Phase diagrams  (Read 4913 times)

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unleash10

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Phase diagrams
« on: February 02, 2006, 08:02:29 PM »
A while back I remember that the phase diagram of water tells us that liquid water is denser than solid water because of its downward slope for the solid/liquid line. However,I cannot remember why this is so. Can anyone remind me?

Offline plu

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Re:Phase diagrams
« Reply #1 on: February 04, 2006, 01:38:42 PM »
The idea is that if you apply pressure to water as ice, it will eventually turn into liquid water.  On a phase diagram of water, if you trace a vertical line up from any temperature below the triple point, you will see that solid water eventually turns into liquid water, provided that there has been a sufficient increase in pressure.  Therefore, the liquid phase of water must be denser than the solid phase.

Offline Donaldson Tan

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Re:Phase diagrams
« Reply #2 on: February 21, 2006, 11:20:58 PM »
. liquid water is denser than solid water ...
Ice floats on water, isn't it?
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Offline mike

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Re:Phase diagrams
« Reply #3 on: February 21, 2006, 11:24:29 PM »
Quote
Ice floats on water, isn't it?

Yes, this is true. We must therfore presume that the water molecules in ice are arrangeed in such a way that they are further apart from each other than in liquid water.

From memory I believe water is most dense at 4C.
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