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Hybridization of triplet carbenes
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Topic: Hybridization of triplet carbenes (Read 1828 times)
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PoetryInMotion
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Hybridization of triplet carbenes
«
on:
September 09, 2013, 10:17:14 AM »
Why are triplet carbenes not sp
3
hybridized? Wouldn't that minimize repoulsion more efficiently than sp
2
or sp hybridization?
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Undergraduate student majoring in chemistry and mathematics. Former IChO participant.
spirochete
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Re: Hybridization of triplet carbenes
«
Reply #1 on:
September 09, 2013, 12:49:42 PM »
There's a good full explanation here:
http://www.chemicalforums.com/index.php?topic=28146.0
My quick and dirty explanation: generally organic molecules want to give filled orbitals more S character. There is more to consider then simply electron repulsion. I'm not sure if this is the best way to think about it but it rationalizes a lot of hybridization.
«
Last Edit: September 09, 2013, 01:06:32 PM by spirochete
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Hybridization of triplet carbenes