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Topic: crystallization temperatures  (Read 2053 times)

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Offline Radu

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crystallization temperatures
« on: November 10, 2013, 02:57:13 PM »
    There are two solutions, containing (NPCl2)n and (NPCl2)n+1. Determine n, considering that the weight percentages of the substances in the two solutions are equal and that the differences between crystallization temperatures of this solutions relate as Δt1:Δt2=0.75:1.
      I don't understand why they use the formula Δt=(k*ω*1000)/(100-ω)*μ . It appears to me that the formula is derived from   the dropping of the freezing point, but the constant includes ΔfusionH, which is not the same for the two substances.
     They simply divide and obtain  Δt1:Δt221. then where does this formula come from?(ω-weight percentage, it is specified.
     

Offline Borek

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Re: crystallization temperatures
« Reply #1 on: November 10, 2013, 03:22:34 PM »
Cryoscopic constant is a function of enthalpy of fusion of the pure solvent, not of the solute.
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Offline Radu

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Re: crystallization temperatures
« Reply #2 on: November 10, 2013, 03:33:41 PM »
Surely, thanks! :)

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