December 28, 2024, 01:16:52 AM
Forum Rules: Read This Before Posting


Topic: Calculating enthalpy change for two solution mixture  (Read 5825 times)

0 Members and 1 Guest are viewing this topic.

Offline KYR_Singularity

  • Very New Member
  • *
  • Posts: 2
  • Mole Snacks: +0/-0
Calculating enthalpy change for two solution mixture
« on: February 11, 2014, 03:13:53 PM »
25.0 cm3 of 2.00 mol dm-3 HCl(aq) was mixed with 25.0 cm3 of 2.00 mol dm-3 NaOH(aq). The temperature increased from 22.5°C to 34.5°C. Find the enthalpy change of reaction for the following equation:
HCl(aq) + NaOH(aq) → NaCl(aq) + H2O(l).
 
how do you work out the energy change in this reaction ?
please show all the work out  , thank you

Offline zsinger

  • Full Member
  • ****
  • Posts: 374
  • Mole Snacks: +18/-60
  • Gender: Male
  • Graduate Chemist
Re: Calculating enthalpy change for two solution mixture
« Reply #1 on: February 11, 2014, 06:15:26 PM »
See:  Hess's Law.  Theres your hint….now lets see some work :)
        Zack
"The answer is of zero significance if one cannot distinctly arrive at said place with an explanation"

Offline KYR_Singularity

  • Very New Member
  • *
  • Posts: 2
  • Mole Snacks: +0/-0
Re: Calculating enthalpy change for two solution mixture
« Reply #2 on: February 12, 2014, 05:22:10 PM »
HCL + NaOH -> NaCl + H2O
(25+25) x 4.18 x 12 = 2508 J
25 Volume reacted
25 x2 / 1000 = 0.05 mol
2508/0.05=50.16KJ/mol
^H = -50.16KJ/mol
is this right ? thanks for the tip anyway  :D

Offline Borek

  • Mr. pH
  • Administrator
  • Deity Member
  • *
  • Posts: 27887
  • Mole Snacks: +1816/-412
  • Gender: Male
  • I am known to be occasionally wrong.
    • Chembuddy
Re: Calculating enthalpy change for two solution mixture
« Reply #3 on: February 12, 2014, 05:41:18 PM »
Doesn't look bad, although you may want to take water produced to the total mass.

Some will consider it nitpicking, but it is almost a 2% difference.
ChemBuddy chemical calculators - stoichiometry, pH, concentration, buffer preparation, titrations.info

Offline zsinger

  • Full Member
  • ****
  • Posts: 374
  • Mole Snacks: +18/-60
  • Gender: Male
  • Graduate Chemist
Re: Calculating enthalpy change for two solution mixture
« Reply #4 on: February 12, 2014, 07:23:38 PM »
Borek is correct.  Otherwise, you got it!
           -Zack
"The answer is of zero significance if one cannot distinctly arrive at said place with an explanation"

Offline Benzene

  • Regular Member
  • ***
  • Posts: 49
  • Mole Snacks: +3/-0
Re: Calculating enthalpy change for two solution mixture
« Reply #5 on: February 12, 2014, 08:18:19 PM »
In Hess's Law, it states that the sum δH products-δH reactants = δH reaction
Is the δH of the products and reactants calculated from the δH of formation? or combustion?

Offline zsinger

  • Full Member
  • ****
  • Posts: 374
  • Mole Snacks: +18/-60
  • Gender: Male
  • Graduate Chemist
Re: Calculating enthalpy change for two solution mixture
« Reply #6 on: February 12, 2014, 09:23:09 PM »
(heats of formation of products) and subtract (heats of formation from reactants).  Thank you Mr. Hess…..may I have another?   :).  Heats of formation.
        -Z
"The answer is of zero significance if one cannot distinctly arrive at said place with an explanation"

Sponsored Links