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Topic: carbonyl reactions (Read 6265 times)
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Benzene
Regular Member
Posts: 49
Mole Snacks: +3/-0
Re: carbonyl reactions
«
Reply #15 on:
February 15, 2014, 06:56:52 PM »
Your ending structure has one hemiacetal, and one ortho ester, they are unstable groups in acid.
You were on the right track initially attacking the carbonyl.
This link will help but it might take some of the challenge away:
http://www.organic-chemistry.org/protectivegroups/carbonyl/dioxanes-dioxolanes.htm
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Penguinone
Regular Member
Posts: 31
Mole Snacks: +1/-0
Re: carbonyl reactions
«
Reply #16 on:
February 15, 2014, 07:31:12 PM »
Thank you for your reply.
Attempt four: see below.
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discodermolide
Chemist
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Re: carbonyl reactions
«
Reply #17 on:
February 15, 2014, 07:42:58 PM »
How does Lithium borohydride react with esters?
Not to give the product you have drawn.
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Penguinone
Regular Member
Posts: 31
Mole Snacks: +1/-0
Re: carbonyl reactions
«
Reply #18 on:
February 15, 2014, 07:54:35 PM »
Thank you for your reply.
Attempt five, see below:
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discodermolide
Chemist
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Re: carbonyl reactions
«
Reply #19 on:
February 15, 2014, 08:01:09 PM »
Yes, you got it, great!
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carbonyl reactions