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Apart from KMnO4, can alkaline H2O2 be used to effect oxidation of C=C
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Topic: Apart from KMnO4, can alkaline H2O2 be used to effect oxidation of C=C (Read 3656 times)
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jmarjorie
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Apart from KMnO4, can alkaline H2O2 be used to effect oxidation of C=C
«
on:
March 14, 2006, 06:10:07 AM »
Dear All,
Apart from KMnO4, can alkaline H2O2 be used to effect oxidation of C=C
at room temp ?
If yes, what are the ideal reaction conditions,catalysts,yields,precautions ?
Any journal references ?
Thanks in advance,
jmarjorie
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Last Edit: March 15, 2006, 01:31:26 PM by Mitch
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Re:OXIDATION OF ALKENES
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Reply #1 on:
March 14, 2006, 01:03:23 PM »
You tend to get epoxides from that kind of reaction, not the C-C bond cleavage products you get with permanganate. The epoxidation reaction with H
2
O
2
is relatively slow when it comes to unactivated alkenes.
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Apart from KMnO4, can alkaline H2O2 be used to effect oxidation of C=C