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Topic: Simple Decarboxylation Question  (Read 1908 times)

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Offline Kylle

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Simple Decarboxylation Question
« on: March 12, 2014, 05:58:01 PM »
Hi Chemestry Forums
Im sorry if this should have ben in the high school chemestry section, didnt know where to put it.

well its accualy very simple, i have a molucule where i have a carbon bounded to a carboxyl group, the problem is that i dont know how to remove it
so instead of C-CO2H then  C-H

if anyone know please contack me
aigen im sorry for my bad english are german, and sorry if it is in the  wrong section ;)
and yes i am very bad at chemestry

Offline sjb

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Re: Simple Decarboxylation Question
« Reply #1 on: March 13, 2014, 02:49:54 AM »
Hi Chemestry Forums
Im sorry if this should have ben in the high school chemestry section, didnt know where to put it.

well its accualy very simple, i have a molucule where i have a carbon bounded to a carboxyl group, the problem is that i dont know how to remove it
so instead of C-CO2H then  C-H

if anyone know please contack me
aigen im sorry for my bad english are german, and sorry if it is in the  wrong section ;)
and yes i am very bad at chemestry

Some compounds will decarboxylate more readily than others. Can you let us know what else there is in your molecule?

See for instance http://en.wikipedia.org/w/index.php?title=Decarboxylation&oldid=594469431 (or the German equivalent at http://de.wikipedia.org/w/index.php?title=Decarboxylierung&oldid=126567309 )

Offline zsinger

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Re: Simple Decarboxylation Question
« Reply #2 on: March 14, 2014, 01:12:08 PM »
Kolbe, Hunsdieker (nasty), Barton-McCombie, Kochi is all I know of.  None are easy, nor fun.  Yields suffer greatly unless you have a very advanced mantle which will keep a super exact temperature.  Otherwise, hydrocarbon cracking.
                  -Z
"The answer is of zero significance if one cannot distinctly arrive at said place with an explanation"

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