December 23, 2024, 07:29:23 AM
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Topic: Can someone please tell me what this question is asking? {heat of formation}  (Read 1581 times)

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Offline maloosh

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"Use your experimental results to calculate the molar heat of reaction for the reaction of calcium with water in Kj/mol of calcium used. Using this value, and the value of the heat of reaction for the equation H2 + 1/2 O2 --> H20

Calculate the molar heat of formation of calcium hydroxide   Ca (s) + O2 + H2 ---> Ca(OH)2 (s) + H2(g) "

the part I don't understand is the last part "Calculate the molar heat of formation". Isn't that the Sum of products- Sum of reactants equation? Or are we using Hess's law?

If it was indeed sum of p- sum of r, how would you do it using two different chemical equations as shown above? I've only been taught to do it with one chemical equation.
« Last Edit: March 29, 2014, 08:01:45 AM by Arkcon »

Offline mjc123

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It's a Hess's law problem. Given the 2 heats of reaction mentioned, you can work out the heat of formation using a Hess's law cycle. (Be careful about stoichiometry.) Your quoted equation doesn't balance. Write Ca + O2 + 2H2  :rarrow: Ca(OH)2 + H2. The reason for the extra mole of hydrogen will become clear when you set up the Hess's law cycle.
In general, the heat of a reaction can be expressed as Σ ΔHform(products) - Σ ΔHform(reactants). But in this case, as all the reactants are pure elements, their heat of formation is zero, so the expression reduces to ΔHform(Ca(OH)2) = ΔHform(Ca(OH)2).

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