I don't know what to say, it is all there, just maybe not organized so you can see it. But lets try:
You'll be given an HCl solution, approx. 0.100 M, what would you use to determine its concentration? It should be about 0.100 M, but how do you accurately measure a gas -- HCl to dissolve it in water?
But you know that NaOH reacts with acids to neutralize them. But how sure are you of it's concentration? It says its 0.125, but NaOH reacts with CO2 in the air.
The thing that may not be obvious at first, is that solid potassium biphthlate, that is exactly known -- or as good as your weighing of the dry pure solid can be.
So now that I've explained it backwards, can you figure it out stepwise forward?