Acetal chemistry is a great example, and so is: (1) Fischer esterification; (2) Aldol chemistry; (3) imine formation; (4) transesterification; (5) cyanohydrin formation, etc.
Many reactions taking place in mammalian systems are equilibrium reactions.
The most important thing to understand is what constitutes an equilibrium reaction, and it's not simply "
"
If you have an intermediate or product that, when placed into the conditions of the original reaction, leads to formation of earlier intermediates and/or starting material, then you have an equilibrium process.
Think Le Chatlier's Principle, what it means, and how it can be utilized in a lab. You'll then be led to the most common "trick" not in the book.