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Topic: Polar Organic Solvents that do not Dissolve CO2  (Read 1963 times)

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Offline ejnov

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Polar Organic Solvents that do not Dissolve CO2
« on: October 31, 2014, 02:40:36 PM »
I'm reading a research paper about the separation of polymers from CO2 during a manufacturing process. Are there any polar organic solvents that do not dissolve CO2 well (i.e. less than a few mg/L at RTP)? This will be very helpful for my research.

Thank You,

Ej


Offline zsinger

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Re: Polar Organic Solvents that do not Dissolve CO2
« Reply #1 on: November 04, 2014, 05:54:00 AM »
You are likely confused.  I think you are speaking of SUPERCRITICAL fluid acting as an extraction media, which is it.  This can be seen in the de-caffenation of coffee beans.  If that is not what you were asking, sorry :)
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Offline Archer

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Re: Polar Organic Solvents that do not Dissolve CO2
« Reply #2 on: November 06, 2014, 08:30:15 PM »
How is the CO2 contaminating the polymer? is it occluded in the polymer matrix?

If you are using LCO2 or SCO2 (as zsinger suggests) as a solvent then it is usually best to use an aprotic polar solvent and vacuum to pull the residue CO2 out of solution.

If you are occluding CO2 during processing though, any solvent is going to be harder to remove than a substance which is naturally a gas at STP.

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