April 04, 2025, 11:24:22 AM
Forum Rules: Read This Before Posting


Topic: X ray diffraction calculation help  (Read 2902 times)

0 Members and 1 Guest are viewing this topic.

Offline poonilization

  • Regular Member
  • ***
  • Posts: 35
  • Mole Snacks: +1/-0
X ray diffraction calculation help
« on: January 14, 2015, 03:02:13 AM »
So here's the question: http://i.gyazo.com/fdaea1eb54bdd3debf0b649ec4b5f807.png

i just need someone to check if i've done the first part correct. I seem to be getting different answers to my friends and i'm not sure where i've gone wrong.

So heres my calculations.

The first compound is body centred so h+k+l = even number so the first 3 hkl values will be (110), (101), (011)

http://i.gyazo.com/ba3ce1f425ea2d3b824b38eefb4062b7.jpg

My friends have managed to get a value of 5.30 Angstroms for hkl (110), i'm not sure who's correct. Can someone confirm the correct answer using hkl (110) and i should be able to do the rest.


« Last Edit: January 18, 2015, 06:26:21 PM by Arkcon »

Offline gritch

  • Regular Member
  • ***
  • Posts: 60
  • Mole Snacks: +8/-0
  • Gender: Male
  • Graduate Student: Inorganic Chemistry
Re: X ray diffraction calculation help
« Reply #1 on: January 18, 2015, 02:31:00 PM »
I'm not overly familiar with the (h,k,l) calculations. I'm actually just learning them myself but everything looks good to me. You however have made a math error:

1dhkl2=h2a2+k2b2+l2c2  :rarrow: (dhkl)2a2h2+b2k2+c2l2

You can't simply invert both sides of the equation like this with addition of fractions. It'd be like saying:

11=13+13+13  :rarrow: 1131+31+31

If you correct this error you'll get 5.30Å in agreement with your friend. Hope that helped but given the delay I suspect you've already figured the issues out by now.

Sponsored Links