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Topic: Oxidation reduction for acidic solution  (Read 3906 times)

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unleash10

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Oxidation reduction for acidic solution
« on: April 06, 2006, 09:46:59 PM »
Here is the overal reaction:
H2C2O4 + AuCl4- --------> H2CO2 + Au + Cl2
So the reduction part is:
H2C204----->2H2CO2; Where carbon is being reduced
Im guessing the oxidation part is
AuCl4-----> Au + 2Cl2
The question i have is Au is being reduced by 3e- but Cl is being oxidized by 4e-. Should i put only 4e- on the right hand, or should i put both 3e- on the left and 4e- on the right and have it cancel out to become 1e- on the right hand?

Offline Albert

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Re:Oxidation reduction for acidic solution
« Reply #1 on: April 07, 2006, 05:44:23 AM »
Try writing the three half-reactions.
« Last Edit: April 07, 2006, 05:46:13 AM by Albert »

Offline AWK

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Re:Oxidation reduction for acidic solution
« Reply #2 on: April 07, 2006, 08:52:45 AM »
I doubt if this reaction can proceed this way
3H2C2O4 + 2AuCl4- + 2H+--------> 3CO2 + 2Au + 8HCl
is more reliable
AWK

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