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Topic: Alkene oxidation with H2O2  (Read 1763 times)

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Offline mmx_01

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Alkene oxidation with H2O2
« on: February 09, 2015, 06:09:29 AM »
With all apology... I understand that carbon hyper acids oxidize alkenes through oxygen migration from C-O-O-H chain to C=C in a sort of concerted electron shift. Ok. But will a similar migration take place if we replace hyperacid with simple H2O2? In general - migration of "underreduced" oxygen is sort of common place for oxygen reactivity - or we need to arrange for some sort of "due allocation of fragments" - such as hydrogen shift to carbonyl oxygen in case of hyper acids - for the process to happen.

Offline Hunter2

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