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Topic: Reduction of Hydrogen atoms on Nitogen  (Read 1261 times)

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Offline ramboacid

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Reduction of Hydrogen atoms on Nitogen
« on: April 21, 2015, 04:46:22 PM »
Why is it possible that we can reduce the hydroxyl hydrogen in an alcohol using solid Na or K to make alkoxides, but we can't do so with the hydrogens in amine compounds?

I have a hunch this has to do with the fact that oxygen-bound H atoms are more acidic than nitrogen-bound H atoms, but I'm curious to whether there's more to the question, and if it's related to the phenomenon of solvated electrons in ammonia solutions.
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