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TPAP,NMMO : mecanism
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Topic: TPAP,NMMO : mecanism (Read 4944 times)
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faust
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TPAP,NMMO : mecanism
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on:
April 07, 2006, 01:28:00 PM »
Hello,
Another question of mechanism, do you have an idea of the mechanism of a primary alcohol oxyded to an acid via the catalytic couple TPAP/NMMO
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Re: TPAP,NMMO : mecanism
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April 12, 2006, 02:35:52 PM »
The mechanism of this reaction isn't know. You could draw a mechanism similar to the oxidation of alcohols by chromium species, but some research on the TPAP system has suggested that the oxidation may occur through a radical process.
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TPAP,NMMO : mecanism