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Topic: HBr addition to ethene  (Read 1306 times)

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Offline SirReal

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HBr addition to ethene
« on: December 27, 2015, 10:48:16 PM »
I know the semester is over, but I still have a nagging question from some of the material we covered.  I am familiar with the mechanism of HBr addition to alkenes through formation of a carbocation, but how does HBr add to ethene without producing a primary carbocation? I saw a few diagrams in which hydrogen forms a cyclic bond with the two alkene carbons, much like oxygen in epoxides, but this baffles me.  I've never seen a hydrogen atom act that way.  Is there some peculiar mechanism behind the addition of HBr to a molecule containing only 2 carbons?

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