I'm not quite sure what you mean.
If you are suggesting that you might purchase 'colloidal silica' then that will come as a suspension and thus would not need to be 'dissolved'. The suspension will be prevented from gelling during transport and storage by having some alkaline agent as a stabilizer. It will also be more concentrated than you will want in the end. If you neutralize it to the right pH with an acid and/or if you introduce just enough, but not too many, positive ions as a salt then you can get it to gel. If you are too heavy handed about it then it will happen too quickly and you will get flocculated precipitate instead.
So just play around with samples by adding various amounts of water, acid, and possibly salts and just wait and you will have yourself some fine jellies
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As long as the silica content is low the transparency should be high.
Temperature isn't a necessary parameter to fiddle with if you are starting out with colloidal silica.
The instruction I gave before was for sodium silicate. With that you will want to use very hot water to get it to dissolve initially. Then you dilute it, add dilute acid, and wait. You will either form a gel in the one step or you will form a colloidal suspension which you can then get to gel by adding a bit more acid or by adding salts.
I've only ever made my own colloidal suspensions from sodium silicate(easy) or from fumed silica(harder).