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Topic: pH Calculation  (Read 2841 times)

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Offline Amykin

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pH Calculation
« on: March 08, 2016, 07:13:26 PM »
I'm stuck on this problem:

What is the pH of a solution when 15.0 mL of a 0.500 M HF solution is added to 15.0 mL of a 0.250 M HCl. Ka for HF is 6.9 x 10^-4

Thank you for any help on how to proceed  :)

Offline AWK

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Re: pH Calculation
« Reply #1 on: March 08, 2016, 07:25:20 PM »
It is sufficient to calculate pH of HCl after dilution. Even in more exact calculations the ionic strength more changes pH than HF.
AWK

Offline tumblewush

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Re: pH Calculation
« Reply #2 on: March 24, 2016, 04:50:21 AM »
Hey, Amykin  :)

Yes, as AWK pointed out, just using the information from HCl to calculate pH is enough for this question. This is because HF is a weak acid and so won't dissociate all that much in solution (as indicated by the Ka), and so the [H3O]+ from it is negligible in the calculation. But then if you had to calculate the pH as a requirement, then you'd have to move through this using the ICE method, being wary of initial concentrations of your products.

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