The electron configuration for Ag is: [Kr] 4d10 5s1 5p0. The p orbitals are empty. the numbers on top of the orbital name represents the number of electrons in those orbitals. so 5s1 is equal to 1 electron in s orbital in the 5th shell. 4d10 means that there are 10 electron in d orbitals (d subshell) in the 4th main shell.
in the picture you attached, the configuration for outermost shell is shown by orbital diagrams.
in the middle one, it is Ag+ cation, that is, one electron lower than silver atom. So you should eliminate an electron form electrons in the outermost energy level of an atom — in the energy level that is farthest away from the nucleus.(highest n-shell)