-Converted the temps to; 112.778-115.556 C
- used Change Tf=KfM that =12.77m and 30.39m respectfully
Where do you get 12.77m from? (And you mean "respectively")
-calculated molality
-12.77x(342.3)/mol(1kg)/1000g=8.29
-30.39(342.3)/mol(1kg/1000g)=104.02
Not molality (you already calculated that, if wrongly); you mean g solute/g solvent; I don't think there's a name for that. And both calculations are wrong.
-Calculate mass %
-8.29/8.29+1(100)= 89.23%
-30.39/30.39+1(100)=91.04%
Why use g/g for one and molality for the other?
Your approach is correct, but you are just being very careless with the calculations.
Besides, I doubt if boiling point varies linearly with molality at such high concentrations.