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Quote from: jasongnome on September 22, 2016, 09:37:24 AMYou are correct, and the sarcastic linking to "let me google that for you" really wasn't appropriate in this thread IMO. You'd already pointed out why Markovnikov's rule doesn't apply.I haven't seen one with an asymmetrical alkane like this either, normally they ensure that one of the carbon atoms does have more hydrogens. You don't give the full question, I assume this IS a question where the alkene is reacting with an acid or water, because if it isn't then Markovnikov's rule doesn't apply anyway.Assuming that you are reacting that alkene with HX, I would assume you'd get an equal mixture as I can see no reason in the mechanism why either intermediate would be favoured.Let me apologize for that. I simply misread it. I thought the reaction showed 2,2-dimethyl-1-butene, hence my sarcasm. I had simply looked at the example and anticipated the next reaction that was to occur and did not examine the post properly. Again, my error and my apology.
You are correct, and the sarcastic linking to "let me google that for you" really wasn't appropriate in this thread IMO. You'd already pointed out why Markovnikov's rule doesn't apply.I haven't seen one with an asymmetrical alkane like this either, normally they ensure that one of the carbon atoms does have more hydrogens. You don't give the full question, I assume this IS a question where the alkene is reacting with an acid or water, because if it isn't then Markovnikov's rule doesn't apply anyway.Assuming that you are reacting that alkene with HX, I would assume you'd get an equal mixture as I can see no reason in the mechanism why either intermediate would be favoured.